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Reduction of metabolic carbon dioxide is one of the essential steps in physiochemical air revitalization for long-duration manned space missions. Under contract with NASA Johnson Space Center, Hamilton Standard is developing an Advanced Carbon Reactor Subsystem (ACRS) to produce water and dense solid carbon from carbon dioxide and hydrogen. The ACRS essentially consists of a Sabatier Methanation Reactor (SMR) to reduce carbon dioxide with hydrogen to methane and water, a gas-liquid separator to remove product water from the methane, and a Carbon Formation Reactor (CFR) to pyrolyze methane to carbon and hydrogen. The hydrogen is recycled to the SMR, while the produce carbon is periodically removed from the CFR. The SMR is well-developed, while the CFR is under development. In this paper, the fundamentals of the SMR and CFR processes are presented and results of Breadboard CFR testing are reported.

In planning for Exploration missions and developing the required suite of environmental monitors, the difficulty lies in down-selecting a multitude of technology options to a few candidates with exceptional potential. Technology selection criteria include conventional analytical parameters (e.g., range, sensitivity, selectivity), operational factors (degree of automation, portability, required level of crew training, maintenance), logistical factors (size, mass, power, consumables, waste generation) and engineering factors such as complexity and reliability. Other more subtle considerations include crew interfaces, data readout and degree of autonomy from the ground control center. We anticipate that technology demonstrations designed toward these goals will be carried out on the International Space Station, the end result of which is a suite of techniques well positioned for deployment during Exploration missions.

Space-faring crews must have safe breathing air throughout their missions to ensure adequate performance and good health. Toxicological assessment of air quality depends on applicable air-quality standards, measurements of pollutant concentrations, and crew reports of air quality. Samples of air were obtained during ingress and egress of the Zarya and Unity modules on missions 2A and 2A.1. The results from 2A suggest that trace pollutants were at safe levels and that there was good air exchange between the modules. Results from the 2A.1 flight also showed that trace pollutants were at acceptable concentrations; however, there was evidence of inadequate mixing between the modules during the hatch-open operations. Furthermore, the 2A.1 crew reported after the flight that the air quality seemed to cause symptoms during their operations in Zarya, particularly when more than one crewmember was working inside open panels for some time.

A porous plate sublimator (based on an existing Lunar Module LM-209 design) is baselined as a heat rejection device for the X-38 vehicle due to its simplicity, reliability, and flight readiness. The sublimator is a passive device used for rejecting heat to the vacuum of space by sublimating water to obtain efficient heat rejection in excess of 1,000 Btu/lb of water. It is ideally suited for the X-38/CRV mission as it requires no active control, has no moving parts, has 100% water usage efficiency, and is a well-proven technology. Two sublimators have been built and tested for the X-38 program, one of which will fly on the NASA V-201 space flight demonstrator vehicle in 2001. The units satisfied all X-38 requirements with margin and have demonstrated excellent performance. Minor design changes were made to the LM-209 design for improved manufacturability and parts obsolescence.

Technologies for the recycling of water are a primary goal of NASA’s advanced life support programs. Biological processes have been identified as an attractive method for wastewater processing. A fundamental new bioreactor based on a traditional activated sludge process is demonstrated that treats hygiene wastewater using magnetic iron oxide particles agglomerated with microbial cells. In this bioreactor, microbes are suspended in magnetic flocs in a wastewater medium. Instead of a traditional gravity separator used in activated sludge operations, a magnetic separator removes the microbial flocs from the outlet stream. The reactor separation operates continuously, independent of gravitational influences. The reactor has been able to simultaneously remove 98% of high levels of both nitrogenous and organic carbon impurities from the wastewater as well as achieve acceptably low levels of total suspended solids.

Twenty-nine recycled water, eight stored (ground-supplied) water, and twenty-eight humidity condensate samples were collected on board the Mir Space Station during the Phase One Program (1995-1998). These samples were analyzed to determine potability of the recycled and ground-supplied water, to support the development of water quality monitoring procedures and standards, and to assist in the development of water reclamation hardware. This paper describes and summarizes the results of these analyses and lists the lessons learned from this project. Results show that the recycled water and stored water on board Mir, in general, met NASA, Russian Space Agency (RSA), and U.S. Environmental Protection Agency (EPA) standards.

Poly (vinyl chloride) (PVC) matrix membranes which incorporate the ionophore nonactin have been evaluated as cation exchange membranes for ammonium ion transport in an electrolytic cell configuration. Interest exists for the development of cation selective membranes for removal of low levels (<200ppm) of ammonium ions commonly found in recycled effluent streams in such diverse applications as expected in a Space Station and commercial fisheries. Ammonium ions are generated as a decomposition product of urea and over time build up in concentration, thus rendering the water unsuitable for human consumption. Nonactin is commonly used in a PVC matrix for ion-selective electrodes.

The most recent goal of our research program was to identify the optimal features of each of three garments to maintain core temperature and comfort under intensive physical exertion. Four males and 2 females between the ages of 22 and 46 participated in this study. The garments evaluated were the MACS-Delphi, Russian Orlan, and NASA LCVG. Subjects were tested on different days in 2 different environmental chamber temperature/humidity conditions (24°C/H∼28%; 35°C/H∼20%). Each session consisted of stages of treadmill walking/running (250W to 700W at different stages) and rest. In general, the findings showed few consistent differences among the garments. The MACS-Delphi was better able to maintain subjects within a skin and core temperature comfort zone than was evident in the other garments as indicated by a lesser fluctuation in temperatures across physical exertion levels.

Humidity condensate collected and processed in-flight is an important component of a space station drinking water supply. Water recovery systems in general are designed to handle finite concentrations of specific chemical components. Previous analyses of condensate derived from spacecraft and ground sources showed considerable variation in composition. Consequently, an investigation was conducted to collect condensate on the Shuttle while the vehicle was docked to Mir, and return the condensate to Earth for testing. This scenario emulates an early ISS configuration during a Shuttle docking, because the atmospheres intermix during docking and the condensate composition should reflect that. During the STS-89 and STS-91 flights, a total volume of 50 liters of condensate was collected and returned. Inorganic and organic chemical analyses were performed on aliquots of the fluid.

The Orion crew module (CM) is being designed to perform survivable land and water landings. There are many issues associated with post-landing crew survival. In general, the most challenging of the realistic Orion landing scenarios from an environmental control standpoint is the off-nominal water landing. Available power and other consumables will be very limited after landing, and it may not be possible to provide full environmental control within the crew cabin for very long after splashdown. Given the bulk and thermal insulation characteristics of the crew-worn pressure suits, landing in a warm tropical ocean area would pose a risk to crew survival from elevated core body temperatures, if for some reason the crewmembers were not able to remove their suits and/or exit the vehicle. This paper summarizes the analyses performed and conclusions reached regarding post-landing crew survival following a water landing, from the standpoint of the crew's core body temperatures.